Metal mediated template synthesis of ligands
Organometallic compounds e-böcker
World Scientific Pub. Co.
2004
EISBN 9789812794819
The template effect. 1.1. Types of template effects. 1.2. The template effect as a molecular organizer effect. 1.3. Factors affecting the product of a template reaction. 1.4. The negative template effect. 1.5. Advantages of metal template reaction.
Alkylation reactions. 2.1. Alkylation of the nitrogen atom. 2.2. Alkylation of the sulfur atom.
Schiff condensation. 3.1. Mechanistic aspects. 3.2. Open-chain ligands. 3.3. Macrocyclic ligands. 3.4. Cage ligands. 3.5 Compartmental ligands.
Mannich condensation. 4.1. Mechanistic aspects. 4.2 Acyclic ligands. 4.3. Monocyclic ligands. 4.4. Isolated dimacrocycles. 4.5.Condensed polymacrocyclic ligands.
Self condensation of nitriles. 5.1. Phthalocyanines. 5.2. Porphyrins. 5.3. Corrole.
Self-assembled systems. 6.1. Catenanes. 6.2. Rotaxanes. 6.3. Helicates. 6.4. Knots. 6.5. Macrocycles and cages. 6.6. Racks, ladder and grids.
This book surveys the relatively new area of the synthesis of organic ligands when metal ions act as a template. In the last fifty years this field has undergone an explosive development, marked by a great amount of literature. The material in the book has been arranged according to the type of chemical reaction involved. In this frame, the basic principles of metal template reactions and the shape of the molecules are considered. Designed to satisfy the demands of students, young researchers doing their PhDs, and those working in the field of coordination chemistry, the book details the role of the metal ions and the specific properties of the formed complexes. Metal Mediated Template Synthesis of Ligands offers a comprehensive analysis with wide-ranging references and provides an extensive overview of research on metal-directed organic ligands over the past five decades.
Alkylation reactions. 2.1. Alkylation of the nitrogen atom. 2.2. Alkylation of the sulfur atom.
Schiff condensation. 3.1. Mechanistic aspects. 3.2. Open-chain ligands. 3.3. Macrocyclic ligands. 3.4. Cage ligands. 3.5 Compartmental ligands.
Mannich condensation. 4.1. Mechanistic aspects. 4.2 Acyclic ligands. 4.3. Monocyclic ligands. 4.4. Isolated dimacrocycles. 4.5.Condensed polymacrocyclic ligands.
Self condensation of nitriles. 5.1. Phthalocyanines. 5.2. Porphyrins. 5.3. Corrole.
Self-assembled systems. 6.1. Catenanes. 6.2. Rotaxanes. 6.3. Helicates. 6.4. Knots. 6.5. Macrocycles and cages. 6.6. Racks, ladder and grids.
This book surveys the relatively new area of the synthesis of organic ligands when metal ions act as a template. In the last fifty years this field has undergone an explosive development, marked by a great amount of literature. The material in the book has been arranged according to the type of chemical reaction involved. In this frame, the basic principles of metal template reactions and the shape of the molecules are considered. Designed to satisfy the demands of students, young researchers doing their PhDs, and those working in the field of coordination chemistry, the book details the role of the metal ions and the specific properties of the formed complexes. Metal Mediated Template Synthesis of Ligands offers a comprehensive analysis with wide-ranging references and provides an extensive overview of research on metal-directed organic ligands over the past five decades.
